Photophysical Properties of Eu3+ β-Diketonates with Extended π-Conjugation in the Aromatic Moiety
نویسندگان
چکیده
The influence of the degree π-conjugation in biaroylmethane ligands upon Eu3+ luminescence efficiency corresponding neutral tris-complexes was investigated depth. data obtained by both steady-state and time-resolved measurements gave an inside into electronic energy transfer mechanisms abovementioned complexes. It shown that extension π-system naphthalene moiety comparison to phenyl one lead a substantial decrease S1 T1 symmetrical β-diketones, which, turn, led total quantum yield respective results are interest for rational design highly luminescent complexes with NIR-emitting lanthanides, as resonant levels energies low can hardly be sensitized common ligands.
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ژورنال
عنوان ژورنال: Inorganics (Basel)
سال: 2022
ISSN: ['2304-6740']
DOI: https://doi.org/10.3390/inorganics11010015